NMR properties:

Magnetogyric Ratio NMR frequency Natural abundance (NA) Nuclear spin (I) Quadrupole moment (Q) Reference sample
101 Ru -1.37210^7 rad/sT 5.16137MHz 17.06% 5.5 45.7fm²


101 Ru

(L. Ruthenia, Russia) Berzelius and Osann in 1827 examined the residues left after dissolving crude
platinum from the Ural mountains in aqua regia. While Berzelius found no unusual metals, Osann
thought he found three new metals, one of which he named ruthenium. In 1844 Klaus, generally
recognized as the discoverer, showed that Osann's ruthenium oxide was very impure and that it contained
a new metal. Klaus obtained 6 g of ruthenium from the portion of crude platinum that is insoluble in aqua
A member of the platinum group, ruthenium occurs native with other members of the group in ores found
in the Ural mountains and in North and South America. It is also found along with other platinum metals
in small but commercial quantities in pentlandite of the Sudbury, Ontario, nickel-mining region, and in
pyroxinite deposits of South Africa.
The metal is isolated commercially by a complex chemical process, the final stage of which is the
hydrogen reduction of ammonium ruthenium chloride, which yields a powder. The powder is
consolidated by powder metallurgy techniques or by argon-arc welding.
Ruthenium is a hard, white metal and has four crystal modifications. It does not tarnish at room
temperatures, but oxidizes explosively. It is attacked by halogens, hydroxides, etc. Ruthenium can be
plated by electrodeposition or by thermal decomposition methods. The metal is one of the most effective
hardeners for platinum and palladium, and is alloyed with these metals to make electrical contacts for
severe wear resistance. A ruthenium-molybdenum alloy is said to be superconductive at 10.6 K. The
corrosion resistance of titanium is improved a hundredfold by addition of 0.1% ruthenium. It is a
versatile catalyst. Hydrogen sulfide can be split catalytically by light using an aqueous suspension of CdS
particles loaded with ruthenium dioxide. It is thought this may have application to removal of H2S from
oil refining and other industrial processes. Compounds in at least eight oxidation states have been found,
but of these, the +2, +3, and +4 states are the most common. Ruthenium tetroxide, like osmium tetroxide,
is highly toxic. In addition, it may explode. Ruthenium compounds show a marked resemblance to those
of cadmium.