NMR properties:

Magnetogyric Ratio NMR frequency Natural abundance (NA) Nuclear spin (I) Quadrupole moment (Q) Reference sample
51 V 7.0455110^7 rad/sT 26.3029MHz 99.75% 7.5 -5.2fm²

VOCL3 + 5% C6D6

51 V

(Scandinavian goddess, Vanadis) Vanadium was first discovered by del Rio in 1801. Unfortunately, a
French chemist incorrectly declared that del Rio's new element was only impure chromium. Del Rio
thought himself to be mistaken and accepted the French chemists's statement.
The element was rediscovered in 1830 by Sefstrom, who named the element in honor of the
Scandinavian goddess, Vanadis, because of its beautiful multicolored compounds. It was isolated in
nearly pure form by Roscoe, in 1867, who reduced the chloride with hydrogen.
Vanadium of 99.3 to 99.8% purity was not produced until 1922.
Vanadium is found in about 65 different minerals among which are carnotite, roscoelite, vanadinite, and
patronite, important sources of the metal. Vanadium is also found in phosphate rock and certain iron
ores, and is present in some crude oils in the form of organic complexes. It is also found in small
percentages in meteorites.
Commercial production from petroleum ash holds promise as an important source of the element. Highpurity
ductile vanadium can be obtained by reduction of vanadium trichloride with magnesium or with
magnesium-sodium mixtures.
Much of the vanadium metal being produced is now made by calcium reduction of V2O5 in a pressure

vessel, an adaption of a process developed by McKechnie and Seybair.
Natural vanadium is a mixture of two isotopes, 50V (0.24%) and 51V (99.76%). 50V is slightly
radioactive, having a half-life of > 3.9 x 1017 years. Nine other unstable isotopes are recognized.
Pure vanadium is a bright white metal, and is soft and ductile. It has good corrosion resistance to alkalis,
sulfuric and hydrochloric acid, and salt water, but the metal oxidizes readily above 660oC.
The metal has good structural strength and a low fission neutron cross section, making it useful in
nuclear applications.
Vanadium is used in producing rust resistant and high speed tools steels. It is an important carbide
stabilizer in making steels.
About 80% of the vanadium now produced is used as ferrovanadium or as a steel additive. Vanadium foil
is used as a bonding agent in cladding titanium to steel. Vanadium pentoxide is used in ceramics and as a
It is also used to produce a superconductive magnet with a field of 175,000 gauss.